Synthesis, thermal and optical properties of new nanosized polyamides containing N-phenyl- and O-naphthyl-s-triazine rings; part 2 was written by Iskander, Abanob A. F.;Mansour, Elsayed M. E.;Hassan, Hammed H. A. M.. And the article was included in Journal of Macromolecular Science in 2017.Electric Literature of C9H6Cl2N4 The following contents are mentioned in the article:
We report the chem. and properties of two new series of well-defined nano sized spheres aramides-containing N- and O-naphthyl-s-triazines. The polymers were carefully characterized by different techniques including IR, UV, fluorescent emission, elemental, thermal analyses and SEM (SEM). The polymers were readily soluble in polar aprotic solvents while insoluble neither in water nor halogenated solvents. Thermal analyses data up to 900°C showed high thermal behavior and the polymers were classified either as “slow burning polymers” or “self-extinguishing polymers” based on their calculated the limiting oxygen index. Interestingly, the naphthyl/Ph interchange has dramatic improvement on the thermal properties. Obviously, the pyridine/phenylene interchange has no influence on the thermal properties of the addressed polymers. Thermal stability of the aniline-containing polymers proved to be comparable to their naphthylamine analogs. Polymers containing p-phenylene moieties exhibited better thermal results compared to their analogs containing m-phenylene moieties. Benzidine containing polymers and sulfone containing polymers exhibited better thermal stabilities than their analogs containing either ether or methylene flexible linkages. The kinetic data obtained from the nonisothermal decomposition of the prepared polyamides series were also studied. The polymers exhibited emissions ranging from blue to orange wavelength depending on the nature of the signaling unit. The naphthyl/Ph interchange led to either appreciable red-shifted absorptions in some cases or blue-shifted absorptions in other cases and this behavior may be attributed to the contorted, twisted structural nature of the naphthalene ring. Such attracting properties make these polymers good candidates for applications such as processable high-temperature materials and also as heat-resistant polymeric materials. This study involved multiple reactions and reactants, such as 4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine (cas: 2272-40-4Electric Literature of C9H6Cl2N4).
4,6-Dichloro-N-phenyl-1,3,5-triazin-2-amine (cas: 2272-40-4) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Electric Literature of C9H6Cl2N4
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics