Thajudeen, H. published the artcilePhase Transfer Catalysis: Polymerization Kinetics and Mechanism of Methyl Acrylate, Quality Control of 23616-79-7, the publication is International Journal of Polymeric Materials (2008), 57(9), 904-917, database is CAplus.
Kinetics and mechanism of Me acrylate (MA) radical polymerization using KHSO5 as water-soluble initiator in the presence of benzyltributylammonium chloride (BTBAC) as a phase-transfer catalyst were studied. Polymerization was carried out under inert and unstirred conditions at 60±1° in EtOAc/water biphasic medium. The rate of polymerization increased with increasing concentrations of MA, BTBAC and KHSO5. The reaction order with respect monomer, initiator and catalyst was 1.0, 0.5 and 0.5, resp. The rate was independent of ionic strength and pH of the medium. Based on the kinetic evidence, a suitable mechanism is proposed.
International Journal of Polymeric Materials published new progress about 23616-79-7. 23616-79-7 belongs to chlorides-buliding-blocks, auxiliary class Phase Transfer Catalyst, name is N-Benzyl-N,N-dibutylbutan-1-aminium chloride, and the molecular formula is C19H34ClN, Quality Control of 23616-79-7.
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