Djerourou, Abdelhafid published the artcileReactivity of dichlorosilanes with lithium ester enolates: synthesis of 3,3-disubstituted 3-silaglutarates, Name: Dichloro(methyl)(octyl)silane, the publication is Journal of Organometallic Chemistry (1995), 485(1-2), 63-8, database is CAplus.
3,3-Disubstituted 3-silaglutarates were synthesized by reaction of the lithium enolate of Et acetate with dichlorosilanes at -94°. When a Ph group is linked to the silicon atom the reaction in THF gave mainly the silaglutarate. In other cases alkylsilyl ketene acetals were formed in proportions similar to or greater than that of the silaglutarate. The presence of HMPA increased the ratio of C- to O-silylated products and allowed the preparation of 3,3-dialkyl 3-silaglutarates in good yield.
Journal of Organometallic Chemistry published new progress about 14799-93-0. 14799-93-0 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Dichloro(methyl)(octyl)silane, and the molecular formula is C9H20Cl2Si, Name: Dichloro(methyl)(octyl)silane.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
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