Kuhn, Richard; Trischmann, Heinrich published an article in 1958, the title of the article was Trimethylsulfoxonium ion.Synthetic Route of 5034-06-0 And the article contains the following content:
Me2SO (I) (16 g.) and 30 ml. MeI refluxed 3 days gave 25 g. octagonal plates of trimethylsulfoxonium iodide, Me3S+OI- (II), m. 200° (H2O), insoluble in C6H6, Et2O, CHCl3, petr. ether, sparingly soluble in MeOH, soluble in H2O (1.5 g. in 100 ml. at 20°). II shaken with an aqueous suspension of AgCl gave the H2O-soluble chloride, long needles, (MeOH-C6H6); picrate, decompose 210° (H2O); tetraphenylborate, m. 195° (aqueous EtOH). The reineckate, phosphomolybdate, and phosphotungstate are very little soluble Thermal decomposition of II gave I. II shaken with aqueous CO2-free Ag2O gave the oily hydroxide, which in the presence of air crystallized to the bicarbonate or carbonate. Reduction of II with HI gave blue-black crystals of the periodide, Me3S+I3-, which on boiling with H2O yielded iodine and Me3S+I-, identical with an authentic specimen. II (1 g.) and 5 ml. pyridine (III), refluxed 15 min., or the chloride and III refluxed 240 min. at 115°, gave quant. yields of III.MeI and III.MeCl, resp. Similarly II and quinoline gave the corresponding MeI derivative, m. 70-2° (monohydrate) (EtOH). II (2.2 g.), 0.7 g. p-O2NC6H4OH, and 10 g. Ag2O in Me2NCHO shaken 2 days at 20°, CHCl3 added, the mixture filtered, washed with 2N NaOH and H2O, dried, and concentrated gave 78% p-O2NC6H4OMe, m. 55°, b0.1 100-5°. The experimental process involved the reaction of trimethyloxosulphonium chloride(cas: 5034-06-0).Synthetic Route of 5034-06-0
trimethyloxosulphonium chloride(cas:5034-06-0) belongs to chlorides. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst. Synthetic Route of 5034-06-0
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics