Creighton, John A.; Green, John Henry Spencer; Harrison, David John published an article in 1969, the title of the article was Vibrational spectra of some trimethylsulfoxonium salts, -h9 and -d9.Product Details of 5034-06-0 And the article contains the following content:
The ir (3650-40 cm.-1) and Raman spectra of (CD3)3,SOI as a solid, Raman data for Me3SOCl and Me3SOI as salts and for the former in aqueous solution have been obtained, and the ir spectra recorded to 50 cm.-1 For the cations there are 36 fundamentals which for C3v geometry divide by Γ = 8 a1 + 4a2 + 12e. The previous interpretation of Me3SOI (C., et al., 1967) is largely confirmed by the new results. The frequencies 1339 and 1318 cm.-1 are now taken as a1 and e, resp., rather than as the reverse of this since, for the corresponding Raman lines of the chloride in solution, that at 1348 cm.-1 appears polarized while that at 1313 cm.-1 is depolarized. The ν (C-S) modes are observed in the Raman spectra. A feature of particular note in the Raman spectrum of solid Me3SOI is the prominent line at 1371 cm.-1 which appears to have its counterpart for (CD3)3SOI at 990 cm.-1 The corresponding ir bands are very weak. Comparison is made with the fundamental frequencies for the isoelectronic mol. (CH3)3PO, with small changes in the assignment. The experimental process involved the reaction of trimethyloxosulphonium chloride(cas: 5034-06-0).Product Details of 5034-06-0
The Article related to vibrations methylsulfoxoniums, ir methylsulfoxoniums, raman methylsulfoxoniums, methylsulfoxoniums spectra, sulfoxoniums spectra, and other aspects.Product Details of 5034-06-0
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics