On December 31, 2021, Vinolia, M.; Kirupavathy, S. Shahil; Jerusha, Eunice; Muthu, S.; Shyam Kumar, M. Infant published an article.Recommanded Product: 99-60-5 The title of the article was Structure, hirshfeld surface studies, optical and mechanical analysis on a third-order nonlinear optical crystal 2-amino-6-methylpyridin-1-ium 2-chloro-4-nitrobenzoate (2A6M2C4N). And the article contained the following:
Organic third order nonlinear optical material, 2-Amino-6-methylpyridin-1-ium 2-chloro-4-nitrobenzoate (2A6M2C4N) was effectively synthesized and single crystals were developed by slow cooling solution growth method. The crystallog. structure of the grown crystal has been confirmed through single crystal X-ray diffraction anal. and it uncovers that the title material belongs to Triclinic crystal system with centrosym. space group of P-1. The crystalline phase formation was ascertained from powder X-ray diffraction measurements. The functional groups present in the compound were confirmed by Fourier transform IR anal. Optical anal. explicit that the grown crystal possess good transmittance in the wave length region of 200-800 nm. Photoluminescence spectroscopy analyzed by exciting the material at 320 nm supports that 2A6M2C4N crystal suits the requirements of optoelectronic devices. The thermal behavior of 2A6M2C4N exploited by TG-DTA measurements show that it is stable up to 160.04 °C. Third order nonlinear optical properties such as nonlinear refractive index and third order nonlinear optical susceptibility were calculated by employing the z-scan technique. The HOMO-LUMO, mol. electrostatic potential (MESP) and contour map of the mol. was examined at B3LYP/6-311++G (d, p) level by using DFT calculations The existence of the intermol. interactions in the mol. were confirmed by Hirshfeld surface studies. The experimental process involved the reaction of 2-Chloro-4-nitrobenzoic acid(cas: 99-60-5).Recommanded Product: 99-60-5
The Article related to nonlinear optics crystal growth hirshfeld analysis slow cooling technique, density functional theory, Placeholder for records without volume info and other aspects.Recommanded Product: 99-60-5
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Chlorides – an overview | ScienceDirect Topics