On August 20, 2009, Mangion, Ian K.; Nwamba, Ikenna K.; Shevlin, Michael; Huffman, Mark A. published an article.Category: chlorides-buliding-blocks The title of the article was Iridium-Catalyzed X-H Insertions of Sulfoxonium Ylides. And the article contained the following:
The unique reactivity of sulfoxonium ylides as a carbene source is described for a variety of X-H bond insertions, taking advantage of a simple, com. available iridium catalyst. This method has applications in both intra- and intermol. reactivity, including a practical ring-expansion strategy for lactams. The safety and stability of sulfoxonium ylides recommend them as preferable surrogates to traditional diazo ketones and esters. The experimental process involved the reaction of trimethyloxosulphonium chloride(cas: 5034-06-0).Category: chlorides-buliding-blocks
The Article related to sulfoxonium ylide iridium catalyst insertion reaction, General Organic Chemistry: Synthetic Methods and other aspects.Category: chlorides-buliding-blocks
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics