Leggio, Antonella; De Marco, Rosaria; Perri, Francesca; Spinella, Mariagiovanna; Liguori, Angelo published an article in 2012, the title of the article was Unusual Reactivity of Dimethylsulfoxonium Methylide with Esters.Name: trimethyloxosulphonium chloride And the article contains the following content:
Dimethylsulfoxonium methylide was treated with esters under mild conditions to rapidly afford the corresponding carboxylic acids at room temperature Moreover, by performing the procedure on enantiopure substrates, it was demonstrated that the reaction occurs without racemization. 18O-labeled reagents showed that the reaction does not proceed through an ester hydrolysis mechanism. The reactions are characterized by an unusual reactivity of the dimethylsulfoxonium methylide. This methodol. is general and can be considered a valid alternate route for ester cleavage when a substrate is sensitive to hydrolysis conditions. The experimental process involved the reaction of trimethyloxosulphonium chloride(cas: 5034-06-0).Name: trimethyloxosulphonium chloride
The Article related to dimethylsulfoxonium methylide ester cleavage, carboxylic acid preparation mechanism, General Organic Chemistry: Synthetic Methods and other aspects.Name: trimethyloxosulphonium chloride
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics