On March 20, 2015, Gou, Quan; Zhang, Zhao-Fu; Liu, Zhi-Cheng; Qin, Jun published an article.HPLC of Formula: 35444-44-1 The title of the article was Palladium-Catalyzed Cs2CO3-Promoted Arylation of Unactivated C(sp3)-H Bonds by (Diacetoxyiodo)arenes: Shifting the Reactivity of (Diacetoxyiodo)arenes from Acetoxylation to Arylation. And the article contained the following:
PdCl2(CH3CN)2-catalyzed arylation of unactivated C(sp3)-H bonds using (diacetoxyiodo)arenes as arylation reagents is reported. The reactivity of (diacetoxyiodo)arenes as arylation reagents is enabled in the presence of Cs2CO3 under the reaction conditions. This arylation method is highly efficient and occurs without the use of silver salt. The reaction tolerates a broad substrate scope that was not demonstrated by other silver salt-free C(sp3)-H bond arylation conditions. The synthetic utility of the method is further illustrated in the synthesis of the psychotropic drug phenibut. A detailed mechanism study was conducted to understand the reaction pathway. The experimental process involved the reaction of Methyl 6-chloro-6-oxohexanoate(cas: 35444-44-1).HPLC of Formula: 35444-44-1
The Article related to palladium catalyst cesium carbonate promoted arylation diacetoxyiodoarene, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Hydrocarbons (Saturated and Unsaturated Side Chains) and other aspects.HPLC of Formula: 35444-44-1
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