On October 5, 2018, Chen, Hui; Guo, Liangliang; Yu, Shouyun published an article.Formula: C7H11ClO3 The title of the article was Primary, Secondary, and Tertiary γ-C(sp3)-H Vinylation of Amides via Organic Photoredox-Catalyzed Hydrogen Atom Transfer. And the article contained the following:
An efficient strategy for primary, secondary and tertiary aliphatic γ-C(sp3)-H vinylation of amides with alkenylboronic acids is reported. These reactions are catalyzed by visible-light organic photoredox agents. Regioselective γ-C(sp3)-H vinylation of amides is controlled by a 1,5-hydrogen atom transfer of an amidyl radical generated in situ. The experimental process involved the reaction of Methyl 6-chloro-6-oxohexanoate(cas: 35444-44-1).Formula: C7H11ClO3
The Article related to aliphatic amide alkenylboronic acid vinylation photoredox hydrogen atom transfer, unsaturated amide stereoselective preparation, Aliphatic Compounds: Amides, Amidines, Imidic Esters, Hydrazides, and Hydrazonic Esters and other aspects.Formula: C7H11ClO3
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics