On October 25, 2017, Chen, Dian-Feng; Chu, John C. K.; Rovis, Tomislav published an article.Category: chlorides-buliding-blocks The title of the article was Directed γ-C(sp3)-H alkylation of carboxylic acid derivatives through visible light photoredox catalysis. And the article contained the following:
Visible light photoredox catalysis enables direct γ- C(sp3)-H alkylation of saturated aliphatic carbonyl compounds Electron-deficient alkenes are used as the coupling partners in this reaction. Distinguished site selectivity is controlled by the predominant 1,5-hydrogen atom transfer of an amidyl radical generated in situ. The experimental process involved the reaction of (1R,2S,5R)-2-Isopropyl-5-methylcyclohexyl carbonochloridate(cas: 14602-86-9).Category: chlorides-buliding-blocks
The Article related to aliphatic carboxylic acid carbamate regioselective alkylation photocatalysis photoredox, Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes: Radiation Chemistry and Photochemistry and other aspects.Category: chlorides-buliding-blocks
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics