On July 25, 2019, Chatterjee, Shreyosree; Abeykoon, Gayan A.; Chen, Jason S. published an article.HPLC of Formula: 35444-44-1 The title of the article was Three-step synthesis of oxylipins from D. loretense. And the article contained the following:
A three-step convergent synthesis of an immunostimulatory oxylipin was developed using an olefin cross metathesis approach. The alkene fragments were prepared in two steps from com. available starting materials with high stereoselectivity. In particular, an organocatalytic aldehyde α-oxygenation gave high enantioselectivity and yield using as little as 2 mol% catalyst [decanal + TEMPO → I (94%, 92:8 er)]. This synthesis represents the shortest synthesis of any natural product containing the 3-ene-1,2,5-triol moiety and delivers an immunostimulatory oxylipin in 33% overall yield. The experimental process involved the reaction of Methyl 6-chloro-6-oxohexanoate(cas: 35444-44-1).HPLC of Formula: 35444-44-1
The Article related to oxylipin synthesis enantioselective organocatalytic aldehyde oxygenation olefin cross metathesis, Biomolecules and Their Synthetic Analogs: Prostaglandins and Other Arachidonic Acid Cascade Substances, Thromboxanes, Fatty Acids and other aspects.HPLC of Formula: 35444-44-1
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