On August 25, 2017, Bender, Matthias; Turnbull, Ben W. H.; Ambler, Brett R.; Krische, Michael J. published an article.Electric Literature of 14602-86-9 The title of the article was Ruthenium-catalyzed insertion of adjacent diol carbon atoms into C-C bonds: Entry to type II polyketides. And the article contained the following:
Current catalytic processes involving carbon-carbon bond activation rely on π-unsaturated coupling partners. Exploiting the concept of transfer hydrogenative coupling, we report a ruthenium(0)-catalyzed cycloaddition of benzocyclobutenones that functionalizes two adjacent saturated diol carbon-hydrogen bonds. These regio- and diastereoselective processes enable convergent construction of type II polyketide substructures. The experimental process involved the reaction of (1R,2S,5R)-2-Isopropyl-5-methylcyclohexyl carbonochloridate(cas: 14602-86-9).Electric Literature of 14602-86-9
The Article related to benzocyclobutenone cycloaddition ruthenium catalyzed, polyketide preparation cycloaddition ruthenium catalyzed, Biomolecules and Their Synthetic Analogs: Others, Including Purines, Pyrimidine Nucleic Acid Bases, Flavins, Lignans and other aspects.Electric Literature of 14602-86-9
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