On November 30, 2010, Sinisi, Riccardo; Sun, Jianwei; Fu, Gregory C. published an article.Recommanded Product: 35444-44-1 The title of the article was Phosphine-catalyzed asymmetric additions of malonate esters to γ-substituted allenoates and allenamides. And the article contained the following:
Because carbonyl groups are ubiquitous in organic chem., the ability to synthesize functionalized carbonyl compounds, particularly enantioselectively, is an important objective. We have developed a straight forward and versatile method for catalytic asym. carbon-carbon bond formation at the γ-position of carbonyl compounds, specifically, phosphine-catalyzed additions of malonate esters to γ-substituted allenoates and allenamides. Mechanistic studies have provided insight into the reaction pathway. The experimental process involved the reaction of Methyl 6-chloro-6-oxohexanoate(cas: 35444-44-1).Recommanded Product: 35444-44-1
The Article related to malonate ester phosphine catalysis asym addition allenoate allenamide, Physical Organic Chemistry: Stereochemistry and Stereochemical Relationships, Including Conformational Inversions and Rotational Isomerization and other aspects.Recommanded Product: 35444-44-1
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics