On May 31, 2022, Ma, Jiajia; Chen, Shuming; Bellotti, Peter; Wagener, Tobias; Daniliuc, Constantin; Houk, Kendall N.; Glorius, Frank published an article.Quality Control of 2-Amino-4-chlorobenzoic acid The title of the article was Facile access to fused 2D/3D rings via intermolecular cascade dearomative [2+2] cycloaddition/rearrangement reactions of quinolines with alkenes. And the article contained the following:
Two types of energy-transfer-mediated cascade dearomative [2+2] cycloaddition/rearrangement reactions of quinoline derivatives with alkenes, which provide a straightforward avenue to 2D/3D pyridine-fused 6-5-4-3- and 6-4-6-membered ring systems are reported. Notably, this energy-transfer-mediated strategy features excellent diastereoselectivity that bypasses the general reactivity and selectivity issues of photochem. [2+2] cycloaddition of various other aromatics Tuning the aza-arene substitutions enabled selective diversion of the iridium photocatalyzed energy transfer manifold towards either cyclopropanation or cyclobutane-rearrangement products. D. functional theory calculations revealed a cascade energy transfer scenario to be operative. The experimental process involved the reaction of 2-Amino-4-chlorobenzoic acid(cas: 89-77-0).Quality Control of 2-Amino-4-chlorobenzoic acid
The Article related to quinoline alkene iridium photochem diastereoselective intermol dearomative cycloaddition rearrangement, azatetracyclododecatriene preparation, tetrahydro benzocyclobutapyridine preparation and other aspects.Quality Control of 2-Amino-4-chlorobenzoic acid
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Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics