On February 28, 1990, Lin, Ivan J. B.; Lai, J. S.; Liu, C. W. published an article.COA of Formula: C3H9ClOS The title of the article was Phase-transfer-catalyzed phosphorus-carbon bond cleavage in platinum bis(diphenylphosphino)methane complexes under exceedingly mild conditions. And the article contained the following:
The reaction of [Pt(dppm)Cl2] (dppm = Ph2PCH2PPh2) with [S(O)Me3]Cl under basic phase-transfer-catalyzed conditions gave the complex {Pt(PPh2Me)[PPh2(OH)][(CH2)2S(O)Me]}Cl, which contains a bidentate sulfur ylide and two monodentate phosphine ligands. The latter was produced by the facile base hydrolysis of the dppm ligand, a reaction that is general for other Pt-dppm complexes. The experimental process involved the reaction of trimethyloxosulphonium chloride(cas: 5034-06-0).COA of Formula: C3H9ClOS
The Article related to carbon phosphorus bond cleavage bisdiphenylphosphinomethane, platinum bisdiphenylphosphinomethane ligand base hydrolysis, sulfur ylide platinum complex, phase transfer catalysis bisdiphenylphosphinomethaneplatinum and other aspects.COA of Formula: C3H9ClOS
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics