Hurst, Timothy E.; Taylor, Richard J. K. published an article in 2017, the title of the article was A Cu-Catalysed Radical Cross-Dehydrogenative Coupling Approach to Acridanes and Related Heterocycles.Electric Literature of 14602-86-9 And the article contains the following content:
The synthesis of acridanes and related compounds through a Cu-catalyzed radical cross-dehydrogenative coupling of simple 2-[2-(arylamino)aryl]malonates is reported. This method can be further streamlined to a one-pot protocol involving the in situ formation of the 2-[2-(arylamino)aryl]malonate by α-arylation of di-Et malonate with 2-bromodiarylamines under Pd catalysis, followed by Cu-catalyzed cyclization. The experimental process involved the reaction of (1R,2S,5R)-2-Isopropyl-5-methylcyclohexyl carbonochloridate(cas: 14602-86-9).Electric Literature of 14602-86-9
The Article related to acridane derivative preparation, arylaminophenylmalonate preparation dehydrogenative coupling copper catalyst, acridanes, copper, cross‐coupling, dehydrogenation, homogeneous catalysis, nitrogen heterocycles, one‐pot reaction and other aspects.Electric Literature of 14602-86-9
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