On February 28, 1981, Goh, Swee Hock; Kam, Toh Seok published an article.Reference of 2-Chloro-4-methyl-1-nitrobenzene The title of the article was Comparative reactivity of substituted 4-nitrobenzylidene dichlorides with alkali. And the article contained the following:
A comparative study of the reactions of RCHCl2 [R = 3,4- and 2,4-Cl(O2N)C6H3, 4-O2NC6H4, 4,3,5-O2N(Me)2C6H2, 2,4-Me(O2N)C6H3] with aqueous-alc. alkali showed that Cl substitution enhances the electron-transfer radical mechanism, whereas Me substitution favors the solvolysis path. The mechanism of the reaction is discussed. The experimental process involved the reaction of 2-Chloro-4-methyl-1-nitrobenzene(cas: 38939-88-7).Reference of 2-Chloro-4-methyl-1-nitrobenzene
The Article related to nitrobenzylidene chloride reactivity alkali, solvolysis nitrobenzylidene chloride, substituent effect reactivity nitrobenzylidene chloride, benzylidene chloride nitro reactivity and other aspects.Reference of 2-Chloro-4-methyl-1-nitrobenzene
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics