On December 31, 1979, Corley, L. S.; Vogl, O. published an article.Application In Synthesis of trimethyloxosulphonium chloride The title of the article was Haloaldehyde polymers. 16. Stabilization of anionically-prepared polychloral by end-capping with decomposable cations and other additives. And the article contained the following:
Completely or partially stable polychloral [25154-92-1] was obtained by anionic cryotachensic polymerization of Cl3CCHO in the presence of alkylating or acylating agents, e.g. Me2SO4 [77-78-1]. Stabilization was also effected by polymerization using salts with easily decomposed cations as anionic initiators. Sulfonium salts, e.g. Me3S+Cl- [3086-29-1] and [Me2S+CH2Ph]Br- [14182-15-1], and iodonium salts, e.g. Ph2I+Cl- [1483-72-3], were effective although quant. stabilization was not achieved. Polychloral with improved stability was also obtained using certain amide acetals, e.g. Me2NCH(OMe)2 [4637-24-5], as initiators. The experimental process involved the reaction of trimethyloxosulphonium chloride(cas: 5034-06-0).Application In Synthesis of trimethyloxosulphonium chloride
The Article related to polychloral stabilization, chloral anionic polymerization stability, sulfonium catalyst chloral polymerization, iodonium initiator chloral polymerization, amide acetal chloral polymerization, end capping polychloral stability and other aspects.Application In Synthesis of trimethyloxosulphonium chloride
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics