Chlorinated organic compounds are found in nearly every class of biomolecules. 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Alkyl chlorides, as versatile building blocks in organic chemistry, are used in the preparation of alcohols, thioethers, alkenes, alkynes, esters, and Grignard reagents. Electric Literature of 12112-67-3.
Wang, Junwei;Zhao, Lin;Li, Caihong;Zhao, Lei;Zhao, Kun;Hu, Yang;Hu, Lihong research published 《 Iridium-Catalyzed [4+3] Cyclization of ortho-Tosylaminophenyl-Substituted para-Quinone Methides with Vinylic Oxiranes/Vinyl Aziridines》, the research content is summarized as follows. An Iridium-catalyzed [4+3] cyclization of ortho-tosylaminophenyl-substituted para-quinone methides with vinylic oxiranes or vinyl aziridines was successfully developed. In the presence of [Ir(cod)Cl]2 and a suitable base, this unprecedented cascade reaction occurred readily in good yield (up to 97%) and high diastereoselectivity (dr>20 : 1), provided a highly efficient synthetic approach to synthetically valuable seven-membered heterocyclic frameworks.
12112-67-3, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
, Electric Literature of 12112-67-3
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics