The class of organic compounds having covalently a bonded chlorine atom is called organic chlorides. 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Their wide structural variety and divergent chemical properties lead to a broad range of named reactions and applications. Reference of 12112-67-3.
Ma, Jie;Idris, Muazzam;Li, Tian Y.;Ravinson, Daniel S. M.;Fleetham, Tyler;Kim, Jongchan;Djurovich, Peter I.;Forrest, Stephen R.;Thompson, Mark E. research published 《 Symmetric “Double Spiro” Wide Energy Gap Hosts for Blue Phosphorescent OLED Devices》, the research content is summarized as follows. Wide energy gap materials dispiro[fluorene-9,9′-anthracene-10′,9″-fluorene] (SAS) and dispiro[xanthene-9,9′-anthracene-10′,9”-xanthene] (XAX) containing double spiro-carbons, are introduced as hosts for blue phosphorescent organic light-emitting diodes (PHOLEDs). Both SAS and XAX are free of heteroat. exocyclic bonds, which are implicated in limiting the stability of blue PHOLEDs. The materials are synthesized in gram-scale quantities through short and efficient paths. They have large energy gaps (≥5.0 eV) between the HOMO (HOMO) and LUMO (LUMO) and correspondingly have high triplet energies in solid state (ET ∼3.0 eV). Anal. of devices using SAS and XAX as host materials with the blue phosphorescent dopant fac-tris(N,N-di-p-tolyl-pyrizinoimidazol-2-yl)iridium(III) (Ir(tpz)3), shows that charges are transported and trapped by the dopant, which subsequently forms excitons directly on the phosphor. As a result, luminescence quenching pathways are suppressed which leads to blue phosphorescent devices with high (∼18%) external quantum efficiency. Thus, SAS and XAX serve as promising host materials, with high triplet energies suitable for blue PHOLEDs.
Reference of 12112-67-3, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
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Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics