《Robust Olefin Metathesis Catalyst Bearing a Tridentate Hemilabile NHC Ligand》 was published in Organometallics in 2020. These research results belong to Yoon, Joseph S.; Cena, Nicolas; Schrodi, Yann. HPLC of Formula: 172222-30-9 The article mentions the following:
An olefin metathesis catalyst bearing a tridentate hemilabile N-heterocyclic carbene (NHC) ligand was synthesized and characterized. The solid-state crystal structure reveals coordination from all three donation sites of the NHC ligand, giving rise to a stable 18-electron complex. Catalytic activity in three standard metathesis reactions was demonstrated, revealing the authors’ catalyst to be particularly long lived and highly selective in the self-metathesis of 1-decene. Although the catalyst in this work initiates more slowly than its 2nd-generation counterparts, it has high thermal stability, yielding peak performances at higher temperatures The unique ligand framework of this catalyst may serve as a template for the synthesis of analogous catalysts with improved efficiencies. The experimental process involved the reaction of Benzylidenebis(tricyclohexylphosphine)dichlororuthenium(cas: 172222-30-9HPLC of Formula: 172222-30-9)
Benzylidenebis(tricyclohexylphosphine)dichlororuthenium(cas: 172222-30-9) is a ruthenium-based olefin metathesis catalyst. It is useful for olefin cross metathesis (CM) and ring closing metathesis (RCM) of terminal olefins under a variety of reactions conditions, and so on.HPLC of Formula: 172222-30-9
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics