Related Products of 5781-53-3In 2021 ,《Zn-Mediated Hydrodeoxygenation of Tertiary Alkyl Oxalates》 was published in Synlett. The article was written by Ye, Yang; Ma, Guobin; Yao, Ken; Gong, Hegui. The article contains the following contents:
A general, mild, and scalable method for hydrodeoxygenation of readily accessible tertiary alkyl oxalates by Zn/silane under Ni-catalyzed conditions was described. The reduction method was suitable for an array of structural motifs derived from tertiary alcs. that beared diverse functional groups, included the synthesis of a key intermediate en route to estrone. After reading the article, we found that the author used Methyl 2-chloro-2-oxoacetate(cas: 5781-53-3Related Products of 5781-53-3)
Methyl 2-chloro-2-oxoacetate(cas: 5781-53-3) belongs to acyl chlorides. Lacking the ability to form hydrogen bonds, acyl chlorides have lower boiling and melting points than similar carboxylic acids. For example, acetic acid boils at 118 °C, whereas acetyl chloride boils at 51 °C. Like most carbonyl compounds, infrared spectroscopy reveals a band near 1750 cm−1.Related Products of 5781-53-3
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics