In 2019,Chemical Science included an article by Joung, Seewon; Bergmann, Allison M.; Brown, M. Kevin. Quality Control of 3-Chlorobenzylchloride. The article was titled 《Ni-catalyzed 1,2-benzylboration of 1,2-disubstituted unactivated alkenes》. The information in the text is summarized as follows:
Nickel-catalyzed 1,2-carboboration of alkenes is emerging as a useful method for chem. synthesis. Prior studies have been limited to only the incorporation of aryl groups. In this manuscript, a method for the 1,2-benzylboration of unactivated alkenes is presented. The reaction combines readily available alkenes, diboron reagents and benzylchlorides to generate synthetically versatile products with control of stereochem. The utility of the products as well as the mechanistic details of the process are also presented.3-Chlorobenzylchloride(cas: 620-20-2Quality Control of 3-Chlorobenzylchloride) was used in this study.
3-Chlorobenzylchloride(cas: 620-20-2) has been used in the reaction of 3-methoxybenzyl chloride and ethyl 4-bromobenzoate in pure water, using zinc dust and a Pd catalyst.Quality Control of 3-Chlorobenzylchloride
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics