Name: 1-(Bromomethyl)-4-chlorobenzeneIn 2021 ,《Tandem Conjugate Addition/Aromatization/Acyl Transfer Reaction between 3-Aryl-2-nitropropanoates and Quinone Monoimines》 appeared in ChemistrySelect. The author of the article were Cheng, Shao-Bing; Liu, Hui; Jing, Yi; Cao, Lian-Yi; Zhang, Xiao-Mei. The article conveys some information:
A tandem conjugate addition/aromatization/acyl transfer reaction between 3-aryl-2-nitropropanoates and quinone monoimines was described. In the presence of NMM, the reaction proceeded smoothly gave various 1,2-diarylnitroethanes in low to good yields. The structure of one product was determined by an X-ray crystal structural anal. Accordingly, a plausible reaction mechanism was proposed. The experimental part of the paper was very detailed, including the reaction process of 1-(Bromomethyl)-4-chlorobenzene(cas: 622-95-7Name: 1-(Bromomethyl)-4-chlorobenzene)
1-(Bromomethyl)-4-chlorobenzene(cas: 622-95-7) undergoes carbonylation in the presence of dimer of chloro(1,5-cyclooctadiene)rhodium(I) to yield the corresponding phenylacetic acid.Name: 1-(Bromomethyl)-4-chlorobenzene It can be synthesized by reacting 4-chlorobenzyl alcohol with bromodimethylsulfonium bromide (BDMS) It can also be synthesized by refluxing a mixture of 4-chlorobenzaldehyde, chlorotrimethylsilane, 1,1,3,3-tetramethyldisiloxane and lithium bromide.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics