SDS of cas: 98-60-2In 2022 ,《Boron-promoted reductive deoxygenation coupling reaction of sulfonyl chlorides for the C(sp3)-S bond construction》 was published in Chinese Chemical Letters. The article was written by Chen, Shuo; Wen, Qingru; Zhu, Yanqing; Ji, Yanru; Pu, Yu; Liu, Zhengli; He, Yun; Feng, Zhang. The article contains the following contents:
Herein, authors report a borane-promoted reductive deoxygenation coupling reaction to synthesize sulfides. This reaction features excellent functional group compatibility, high efficiency, broad substrate scope, and application in late-stage functionalization of biomols. Preliminary mechanistic studies suggest diaryl sulfides are the intermediates of this reaction. Moreover, the real active aryl sulfide anions may be generated in situ with the aid of B2pin2 and react with alkyl tosylates through a concerted SN2 pathway. The experimental part of the paper was very detailed, including the reaction process of 4-Chlorobenzenesulfonyl chloride(cas: 98-60-2SDS of cas: 98-60-2)
4-Chlorobenzenesulfonyl chloride(cas: 98-60-2) belongs to organochlorine compounds. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.SDS of cas: 98-60-2
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics