《Chemoselective synthesis of heterobimetallic bis-NHC complexes》 was published in Dalton Transactions in 2020. These research results belong to Dutschke, Patrick D.; Bente, Stefanie; Daniliuc, Constantin G.; Kinas, Jenny; Hepp, Alexander; Hahn, F. Ekkehardt. COA of Formula: C18H24Cl2N2Pd2 The article mentions the following:
Bis-NHC precursors composed of an azolium and a 2-halogenoazole group connected by different linkers have been site-selectively metalated to give heterobimetallic complexes from a single-frame bis-NHC ligand. The azolium group reacts with a base and oxidized metal centers to give NHC complexes with no participation of the halogenoazole, while the halogenoazole reacts in an oxidative addition with low-valent transition metals to give azolato complexes with no participation of the azolium group. In addition to this study using Di-μ-chlorobis[2-[(dimethylamino)methyl]phenyl-C,N]dipalladium(II), there are many other studies that have used Di-μ-chlorobis[2-[(dimethylamino)methyl]phenyl-C,N]dipalladium(II)(cas: 18987-59-2COA of Formula: C18H24Cl2N2Pd2) was used in this study.
Di-μ-chlorobis[2-[(dimethylamino)methyl]phenyl-C,N]dipalladium(II)(cas: 18987-59-2) belongs to organochlorine compounds. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.COA of Formula: C18H24Cl2N2Pd2
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics