Computed Properties of C7H6Cl2On November 1, 2019 ,《Iron-Catalyzed Cross-Coupling of Functionalized Benzylmanganese Halides with Alkenyl Iodides, Bromides, and Triflates》 appeared in Organic Letters. The author of the article were Desaintjean, Alexandre; Belrhomari, Sophia; Rousseau, Lidie; Lefevre, Guillaume; Knochel, Paul. The article conveys some information:
Various substituted benzylic manganese chlorides e.g. I were prepared by insertion of magnesium turnings in the presence of MnCl2.2LiCl in THF at -5° within 2 h. These benzylic manganese reagents underwent smooth cross-couplings with various functionalized alkenyl iodides, bromides, and triflates or iodoacrylates in the presence of 10 mol % FeCl2 at 25° for 1-12 h. Mechanistic studies showed that benzylic manganese halides produced, in the presence of FeCl2, a very reactive iron ate complex. The experimental process involved the reaction of 3-Chlorobenzylchloride(cas: 620-20-2Computed Properties of C7H6Cl2)
3-Chlorobenzylchloride(cas: 620-20-2) has been used in the reaction of 3-methoxybenzyl chloride and ethyl 4-bromobenzoate in pure water, using zinc dust and a Pd catalyst.Computed Properties of C7H6Cl2
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics