Related Products of 768-35-4In 2019 ,《Enantioselective Synthesis of Triarylmethanes via Organocatalytic 1,6-Addition of Arylboronic Acids to para-Quinone Methides》 appeared in Advanced Synthesis & Catalysis. The author of the article were Huang, Gong-Bin; Huang, Wei-Hua; Guo, Jing; Xu, Dong-Liang; Qu, Xiao-Chen; Zhai, Pei-Hong; Zheng, Xiu-Hua; Weng, Jiang; Lu, Gui. The article conveys some information:
A method for the preparation of chiral triarylmethanes via organocatalytic 1,6-addition of arylboronic acids to para-quinone methides (p-QMs) was established. Here the use of salicylaldehyde-derived p-QMs with an ortho-hydroxy substituent as a directing group was essential for the remote stereocontrol. In the presence of a BINOL catalyst, chiral triarylmethanes, e.g., I, can be obtained in high yields (up to 99%) with excellent enantioselectivities (up to 99% ee). This method shows broad substrate tolerance and can be easily scaled up, both electron-rich and electron-deficient arylboronic acids are suitable substrates for this addition reaction. In the experimental materials used by the author, we found (3-Fluorophenyl)boronic acid(cas: 768-35-4Related Products of 768-35-4)
(3-Fluorophenyl)boronic acid(cas: 768-35-4) can be used to make novel liquid crystalline fluorobiphenylcyclohexenes and difluoroterphenyls by palladium-catalyzed cross-couplings also used in the synthesis of o-phenylphenols as potent leukotriene B4 receptor agonists.Related Products of 768-35-4
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics