In 2019,Organic & Biomolecular Chemistry included an article by Jadhav, Sandip B.; Thopate, Satish B.; Nanubolu, Jagadeesh Babu; Chegondi, Rambabu. Recommanded Product: 768-35-4. The article was titled 《Rh-Catalyzed diastereoselective desymmetrization of enone tethered-cyclohexadienones via tandem arylative cyclization》. The information in the text is summarized as follows:
The rhodium-catalyzed arylative cyclization of enone tethered-cyclohexadienones I (R = Me, Et, i-Pr, (CH2)2OTBS; Ar = C6H5, 4-F3CC6H4, 3-BrC6H4, etc.) has been developed with high efficiency, thus providing cis-fused bicyclic enones II (R = Me, Et, i-Pr, (CH2)2OTBS; Ar = C6H5, 4-F3CC6H4, 3-BrC6H4, etc.; Ar1 = C6H5, 2-MeOC6H4, 4-ClC6H4, etc.) in good yields and with excellent diastereoselectivities. Furthermore, this mild transformation has a broad range of substrate scope and excellent functional group tolerance. In addition, bicyclic products have an enone functionality, which can be a synthetically valuable handle for further transformations. The experimental process involved the reaction of (3-Fluorophenyl)boronic acid(cas: 768-35-4Recommanded Product: 768-35-4)
(3-Fluorophenyl)boronic acid(cas: 768-35-4) can be used to make novel liquid crystalline fluorobiphenylcyclohexenes and difluoroterphenyls by palladium-catalyzed cross-couplings also used in the synthesis of o-phenylphenols as potent leukotriene B4 receptor agonists.Recommanded Product: 768-35-4
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics