Sen, Sudeshna; Goodwin, Sean E.; Barbara, Pedro Verdia; Rance, Graham A.; Wales, Dominic; Cameron, Jamie M.; Sans, Victor; Mamlouk, Mohamed; Scott, Keith; Walsh, Darren A. published the artcile< Gel-Polymer Electrolytes Based on Poly(Ionic Liquid)/Ionic Liquid Networks>, Formula: C9H9Cl, the main research area is gel polymer electrolyte ionic liquid conductivity crosslinking membrane.
The use of elec. charged, polymerized ionic liquids (polyILs) offers opportunities for the development of gel-polymer electrolytes (GPEs), but the rational design of such systems is in its infancy. In this work, we compare the properties of polyIL/IL GPEs based on 1-butyl-3-(4-vinylbenzyl)imidazolium bis(trifluromethanesulfonyl)imide containing trapped ammonium-based protic ionic liquids (ILs) with an analogous series based on the elec. neutral host polymer 1-(4-vinylbenzyl)imidazole. The materials are synthesized by photopolymerizing ionic and neutral monomers in the presence of diethylmethylammonium trifluoromethanesulfonate, [dema][TfO], diethylmethylammonium trifluoroacetate, [dema][TFAc], and diethylmethylammonium bis[trifluoromethanesulfonyl]imide, [dema][Tf2N], resp. The resulting materials are characterized using electron microscopy, IR spectroscopy, thermal anal., Raman spectroscopy, and AC-impedance anal. Spectroscopic anal. confirms that the ILs are distributed throughout the polymers, unless the GPE also contains poly(diallyldimethylammonium) bis[trifluoromethanesulfonyl]imide, when separation of the components occurs. The polyIL/IL GPEs are more electrochem. and thermally stable, and up to six times more conductive, than the materials based on the neutral host. As a proof-of-concept demonstration, we show that polyIL/IL gels can be 3D printed using readily available 3D-printing hardware.
ACS Applied Polymer Materials published new progress about Crosslinking. 1592-20-7 belongs to class chlorides-buliding-blocks, and the molecular formula is C9H9Cl, Formula: C9H9Cl.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics