Hirose, Yuuka; Yamazaki, Mirai; Nogata, Misa; Nakamura, Akira; Maegawa, Tomohiro published the artcile< Aromatic Halogenation Using N-Halosuccinimide and PhSSiMe3 or PhSSPh>, Synthetic Route of 128-09-6, the main research area is arene aromatic halogenation halosuccinimide; haloarene preparation aromatic halogenation halosuccinimide.
We developed a mild aromatic halogenation reaction using a combination of N-halosuccinimide and PhSSiMe3 or PhSSPh. Less reactive aromatic compounds, such as Me 4-methoxybenzoate, were brominated with PhSSiMe3 or PhSSPh and N-bromosuccinimide in high yields. No reaction was observed in the absence of PhSSiMe3 or PhSSPh. This method is also applicable to chlorination reactions using N-chlorosuccinimide and PhSSPh.
Journal of Organic Chemistry published new progress about Anisoles Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 128-09-6 belongs to class chlorides-buliding-blocks, and the molecular formula is C4H4ClNO2, Synthetic Route of 128-09-6.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics