Box, Vernon G. S.; Meleties, Panayiotis C. published the artcile< The thermal [3,3] Claisen rearrangement of the 3-substituted phenyl allyl and propargyl ethers. The synthesis of 4-halobenzo[b]furans>, Computed Properties of 22717-55-1, the main research area is Claisen rearrangement allyl phenyl ether regioselectivity mechanism; propargyl phenyl ether Claisen rearrangement regioselectivity mechanism.
The thermal [3,3] Claisen rearrangement of 3-substituted Ph allyl and propargyl ethers is regioselective. The major product of the reaction incorporates a 1,2,3-trisubstituted benzene ring. The 2-allenylphenol intermediates can be manipulated into the preparation of 4-substituted benzo[b]furans. The observed regioselectivity supports the biradicaloid mechanism of the Claisen rearrangement.
Heterocycles published new progress about Aromatic ethers Role: RCT (Reactant), RACT (Reactant or Reagent). 22717-55-1 belongs to class chlorides-buliding-blocks, and the molecular formula is C8H7ClO3, Computed Properties of 22717-55-1.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics