Zhou, Lu; Zhu, Chuan; Bi, Peijia; Feng, Chao published the artcile< Ni-catalyzed migratory fluoro-alkenylation of unactivated alkyl bromides with gem-difluoroalkenes>, Recommanded Product: 3-Chlorophenethyl Bromide, the main research area is aralkyl bromide aryl difluoroalkene nickel catalyst stereoselective regioselective fluoroalkenylation; diaryl fluoroalkene preparation.
Nickel-catalyzed highly regio- and stereoselective migratory fluoro-alkenylation of unactivated alkyl bromides was reported. Catalytic cycle merged alkyl nickel chain-walking and defluorinative coupling enabled the introduction of a broad array of fluoroalkenyl moieties into carbon chains. Control experiments with other halogenated alkenes demonstrated the essential role of fluorine atoms in this reaction. The reaction proceeded under mild conditions and allowed for the synthesis of a variety of valuable monofluoroalkenes.
Chemical Science published new progress about Alkenylation catalysts, stereoselective. 16799-05-6 belongs to class chlorides-buliding-blocks, and the molecular formula is C8H8BrCl, Recommanded Product: 3-Chlorophenethyl Bromide.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics