Wu, Mingxi; Wang, Mingjin; Cao, Song published the artcile< Copper(I)-catalyzed trifluoromethylation of phthalic anhydride derivatives with (trifluoromethyl)trimethylsilane>, Electric Literature of 118-45-6, the main research area is phthalic anhydride fluoromethylsilane trifluoromethylation copper catalyst; naphthalic anhydride fluoromethylsilane trifluoromethylation copper catalyst; fluoromethylhydroxyisobenzofuran lactone preparation; fluoromethylhydroxynaphthopyranone lactone preparation.
An efficient copper-catalyzed trifluoromethylation of substituted phthalic anhydrides using (trifluoromethyl)trimethylsilane (Me3SiCF3) as a nucleophilic trifluoromethylating reagent in the presence of 1,10-phenanthroline and KF, followed by quenching the reaction mixture with water was developed. A possible mechanism was suggested.
Chinese Journal of Chemistry published new progress about Anhydrides, cyclic Role: RCT (Reactant), RACT (Reactant or Reagent). 118-45-6 belongs to class chlorides-buliding-blocks, and the molecular formula is C8H3ClO3, Electric Literature of 118-45-6.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics