Wang, Yi; Fang, Zaixiang; Chen, Xiaochuan; Wang, Yuanhua published the artcile< Dirhodium(II)-Catalyzed C(sp2)-H Azidation of Benzaldehydes>, Safety of 4-Chloro-2-methoxybenzaldehyde, the main research area is dirhodium complex catalyst preparation crystal structure; aldehyde trimethylsilyl azide regioselective dirhodium complex catalyst; azido aldehyde preparation; aromatic aldehydes; azidation; dirhodium; one-electron oxidation; radicals.
An efficient azidation method mediated by dirhodium(II) catalysts to achieve the direct aryl azidation of aromatic aldehydes avoiding the simultaneous use of protected aldehydes and prefunctionalized arenes was reported. The regioselectivity of this method was similar to those of typical aromatic electrophilic substitution reactions. The resulting azidobenzaldehyde products were versatile building blocks or precursors for the synthesis of many biol. active compounds The mechanism studies indicated that the one-electron oxidative intermediate Rh2(II,III)N3 was responsible for the azide transfer.
Chemistry – A European Journal published new progress about Aldehydes Role: PRP (Properties), RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 53581-86-5 belongs to class chlorides-buliding-blocks, and the molecular formula is C8H7ClO2, Safety of 4-Chloro-2-methoxybenzaldehyde.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics