Trost, Barry M.; Jiao, Zhiwei; Hung, Chao-I. published the artcile< Elaborating Complex Heteroaryl-Containing Cycles via Enantioselective Palladium-Catalyzed Cycloadditions>, HPLC of Formula: 2382-10-7, the main research area is methylenecyclopentane methylenepyrrolidine methylenetetrahydrofuran methylenespirotetrahydrofuranindolon stereoselective preparation; palladium diamidophosphite catalyst regioselective stereoselective cycloaddition heteroaryl allylic carbonate; chalcone nitroalkene aldimine aldehyde stereoselective cycloaddition heteroaryl allylic carbonate; asymmetric catalysis; cycloadditions; heterocycles; palladium; trimethylenemethane.
In the presence of allyl(cyclopentadienyl)palladium and a nonracemic diamidophosphite ligand, allylic carbonates containing heteroaryl and nitrophenyl moieties such as I underwent regioselective, diastereoselective, and enantioselective cycloaddition reactions with chalcones, electron-deficient alkenes, aryl aldimines, and nitrobenzaldehydes or N-methylisatin to yield nonracemic methylenecyclopentanes such as II, methylenepyrrolidines, methylenetetrahydrofurans, and methylenespirotetrahydrofuranindolones. Fused and bridged products were also prepared from nitrocycloalkenes and tropone. Allylic carbonates containing many classes of nitrogen-containing aromatics, including pyridines, quinolines, pyrimidines, various azoles and purines, were compatible substrates.
Angewandte Chemie, International Edition published new progress about Aldimines Role: RCT (Reactant), RACT (Reactant or Reagent). 2382-10-7 belongs to class chlorides-buliding-blocks, and the molecular formula is C6H4Cl2N4, HPLC of Formula: 2382-10-7.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics