Cazotti, Jaime C.; Fritz, Alexander T.; Garcia-Valdez, Omar; Smeets, Niels M. B.; Dube, Marc A.; Cunningham, Michael F. published the artcile< Grafting from Starch Nanoparticles with Synthetic Polymers via Nitroxide-Mediated Polymerization>, Reference of 1592-20-7, the main research area is grafting starch nanoparticle nitroxide mediated polymerization acrylic; grafting from; nitroxide-mediated polymerization; reversible deactivation radical polymerization; starch nanoparticles.
Nitroxide-mediated polymerization (NMP) is employed to graft synthetic polymers from polysaccharides. This work demonstrates the first successful polymer grafting from starch nanoparticles (SNPs) via NMP. To graft synthetic polymers from the SNPs’ surface, the SNPs are first functionalized with 4-vinylbenzyl chloride prior to reaction with BlocBuilder MA yielding a macroinitiator. Me methacrylate with styrene, acrylic acid, or Me acrylate are then grafted from the SNPs. The polymerizations exhibited linear reaction kinetics, indicating that they are well controlled. Thermal gravimetric anal. and spectroscopic techniques confirmed the synthesis of the precursors materials and the success of the grafting from polymerizations The incorporation of hydrophobic synthetic polymers on hydrophilic SNPs yields new hybrid materials that could find use in several industrial applications including paper coatings, adhesives, and paints.
Macromolecular Rapid Communications published new progress about Adhesives. 1592-20-7 belongs to class chlorides-buliding-blocks, and the molecular formula is C9H9Cl, Reference of 1592-20-7.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics