The class of organic compounds having covalently a bonded chlorine atom is called organic chlorides. 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Their wide structural variety and divergent chemical properties lead to a broad range of named reactions and applications. Reference of 12112-67-3.
Canadas, Purificacion;Diaz, Jesus;Perez, Julio;Riera, Lucia research published 《 Strongly Electron-Donating Triazolylidene Ligands: Cationic Metal Carbonyl Complexes of 1-Methyl-1,2,3-triazole as Triazolium Surrogates》, the research content is summarized as follows. A new strategy for tuning the electronic properties of 1,2,3-triazol-5-ylidene metal complexes is reported using {Mo(η3-C4H7)(bipy)(CO)2} or {Re(bipy)(CO)3} fragments as substituents at the triazole N3 atom. Reaction of cationic Mo(II) and Re(I) 1-methyl-1,2,3-triazole compounds with the strong base KN(SiMe3)2 in the presence of electrophilic metal fragments, such as AgOTf (OTf = trifluoromethanesufonate) or [CuCl(IPr)] (IPr = 2,6-(diisopropyl)phenylimidazol-2-ylidene) affords a new type of 1,2,3-triazol-5-ylidene complexes. For Ag(I) cationic bis(triazolylidene)complexes [Ag(tzNHCM)2]OTf (M = [Mo], 2; [Re], 4) were obtained, whereas in the case of Cu(I) mixed normal/mesoionic NHC complexes [Cu(IPr)(tzNHCM)]OTf (M = [Mo], 7; [Re], 8) are formed. This special type of mesoionic N-heterocyclic carbenes bear a metal fragment at the N3 atom of the 1,2,3-triazole moiety, showing a notable enhancement of the carbene electron donor ability compared to conventional alkyl-substituted analogs. Transmetalation from cationic Ag bis(triazolylidene) complexes 2 and 4, prepared using this methodol., proved to be very efficient toward [M’Cl(cod)]2 (M’ = Rh, Ir; cod = cyclooctadiene), affording the corresponding cationic bis(triazolylidene) [M'(cod)(tzNHCM)2]OTf (9–12) complexes. The subsequent reaction with CO(g) produces easily the substitution of the diene ligand, affording the corresponding cis-dicarbonyl [M'(CO)2(tzNHCM)2]OTf (13–16) compounds
Reference of 12112-67-3, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
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Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics