Recommanded Product: 2-((1R,5S)-6,6-Dimethylbicyclo[3.1.1]hept-2-en-2-yl)ethanol. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: 2-((1R,5S)-6,6-Dimethylbicyclo[3.1.1]hept-2-en-2-yl)ethanol, is researched, Molecular C11H18O, CAS is 35836-73-8, about Synthesis and crystal structure of an optically active, internally coordinated alkylchloroborane. The boron-centered anomeric effect. Author is Shiner, Christopher S.; Garner, Charles M.; Haltiwanger, R. Curtis.
The synthesis and crystal structure of (S)-(O-B)-chloro[(1S,2R,3S,5S)-2-[2-(R)-methoxyethyl]-6,6-dimethyl-3-norpinyl]borane, an optically active, internally coordinated alkylchloroborane monomer, are described. This is the 1st crystallog. structure determination for a chiral organoborane, and the 1st complete x-ray anal. of a monoborane-ether complex. Key features of the structure, including the configuration of the stereogenic B atom, the unusually long B-Cl bond (d = 1.890 Å), and the geometry of the trivalent O, are manifestations of a novel B-centered anomeric effect. An improved preparation of BH2Cl.SMe2 was also devised.
Although many compounds look similar to this compound(35836-73-8)Recommanded Product: 2-((1R,5S)-6,6-Dimethylbicyclo[3.1.1]hept-2-en-2-yl)ethanol, numerous studies have shown that this compound(SMILES:CC1(C)[C@@]2([H])CC=C(CCO)[C@]1([H])C2), has unique advantages. If you want to know more about similar compounds, you can read my other articles.
Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics