Synthetic Route of C8H11NO2. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: 1-(tert-Butyl)-1H-pyrrole-2,5-dione, is researched, Molecular C8H11NO2, CAS is 4144-22-3, about Structural Studies on α-Pyrone Cycloadducts. Manifestation of the Early Stages of CO2 Extrusion by retro Hetero-Diels-Alder Reaction. Author is Roth-Barton, Jesse; Goh, Yit Wooi; Karnezis, Asimo; White, Jonathan M..
Structures of the α-pyrone (pyran-2-one) cycloadducts 4-8 show deviations of some bond distances from their normal values, consistent with manifestation of the early stages of the retro hetero-Diels-Alder decarboxylation reaction in the ground state structures. Thus the bridgehead C-O(CO) and C-CO(O) bonds are lengthened and the bridging C-O bond is shortened. The degree of lengthening of the C-O(CO) and C-CO(O) bonds is similar, whereas in the calculated transition state structure there is significant asymmetry in the extent of C-CO(O) and C-O(CO) bond breaking.
As far as I know, this compound(4144-22-3)Synthetic Route of C8H11NO2 can be applied in many ways, which is helpful for the development of experiments. Therefore many people are doing relevant researches.
Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics