Analyzing the synthesis route of 12266-72-7

As far as I know, this compound(12266-72-7)Synthetic Route of C8H12I2Pt can be applied in many ways, which is helpful for the development of experiments. Therefore many people are doing relevant researches.

Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999) called Synthesis and structural studies of some 1,1′-dichloroferrocene derivatives of platinum(II). Crystal and molecular structure of 2,2-μ-[(1-2,5-6-η-cis,cis-1,5-cyclooctadiene)platinio]bis(1,1′-dichloroferrocene), Author is Hollands, Ronald E.; Osborne, Anthony G.; Whiteley, Richard H.; Cardin, Christine J., which mentions a compound: 12266-72-7, SMILESS is I[Pt]I.C1=CCC/C=CCC/1, Molecular C8H12I2Pt, Synthetic Route of C8H12I2Pt.

[Pt(COD)[Fe(C5H4Cl)(C5H3Cl)]nL2-n] (I; COD = 1,5-cyclooctadiene; n = 2; n = 1, L = Me, CH2Ph) were prepared by salt-elimination reactions of 2-lithio-1,1′-dichloroferrocene and haloplatinum complexes. I (n = 1, L = iodo, Br, Cl) were prepared by halogenating I (n = 2). The structure of I (n = 2) was determined by x-ray anal. Results were refined to R 0.0485 for 2553 reflections. I (n = 2) has a DL arrangement of ferrocenyl groups, with a single crystal consisting of mols. of 1 enantiomer.

As far as I know, this compound(12266-72-7)Synthetic Route of C8H12I2Pt can be applied in many ways, which is helpful for the development of experiments. Therefore many people are doing relevant researches.

Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics