Formula: C11H18O. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: 2-((1R,5S)-6,6-Dimethylbicyclo[3.1.1]hept-2-en-2-yl)ethanol, is researched, Molecular C11H18O, CAS is 35836-73-8, about Iron-Catalyzed C-C Single-Bond Cleavage of Alcohols.
An iron-catalyzed deconstruction/hydrogenation reaction of alcs. e.g., 1-(4-methoxyphenyl)cyclohexan-1-ol through C-C bond cleavage was developed through photocatalysis to produce ketones RC(O)R1 [R = Ph, Me, 4-bromophenyl, etc. ; R1 = Et, n-Bu, 3,3-difluoropentyl, etc.; RR1 = (CH2)5]/aldehydes R2CHO (R2 = Ph, cyclopentylmethyl, n-hexyl, etc.) as the products. Tertiary, secondary, and primary alcs. e.g., 1-(4-methoxyphenyl)cyclohexan-1-ol bearing a wide range of substituents are suitable substrates. Complex natural alcs. can also perform the transformation selectively. The investigation of the mechanism reveals a procedure that involves chlorine radical improved O-H homolysis, with the assistance of 2,4,6-collidine.
This literature about this compound(35836-73-8)Formula: C11H18Ohas given us a lot of inspiration, and I hope that the research on this compound(2-((1R,5S)-6,6-Dimethylbicyclo[3.1.1]hept-2-en-2-yl)ethanol) can be further advanced. Maybe we can get more compounds in a similar way.
Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics