Hwang, Joon Young; Ji, A. Young; Lee, Sang Hyeok; Kang, Eun Joo published the article 《Redox-Selective Iron Catalysis for α-Amino C-H Bond Functionalization via Aerobic Oxidation》. Keywords: redox selective iron catalyst aerobic oxidation.They researched the compound: 1-(tert-Butyl)-1H-pyrrole-2,5-dione( cas:4144-22-3 ).Synthetic Route of C8H11NO2. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:4144-22-3) here.
Single-electron oxidation and α-deprotonation of tertiary anilines using Fe(phen)3(PF6)3 afford α-aminoalkyl radicals, which can be coupled with electrophilic partners to afford various tetrahydroquinolines. Mechanistically, the Fe(phen)n2+/3+ catalytic cycle is maintained by O2 or a TBHP oxidant, and the presence of the oxygen bound iron complex, Fe(III)-OO(H), was elucidated by ESR and electrospray ionization mass spectrometry. This redox-selective nonheme iron catalyst behaves similarly to bioinspired heme iron catalysts.
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Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics