Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: Diiodo(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12I2Pt, CAS is 12266-72-7, about Mass spectrometric and X-ray studies on complexes of the type (COD)PtX2 (X = Cl, Br, I, CH3, CH2CMe3, CH2SiMe3).Synthetic Route of C8H12I2Pt.
Investigations by mass spectrometry at complexes of the type (COD)PtX2 (X = Cl (1), Br (2), I (3), Me (4), CH2CMe3 (5) and CH2SiMe3 (6), (COD) = 1,5-cyclooctadiene) show the mole peak of all compounds with the characteristic isotopic pattern of platinum and platinum with chlorine, bromine or silicon resp. The group of peaks of the complexes 1-5 at 300 m/e show a high stability of the (COD)Pt fragment. A new route of synthesis of (COD)PtBr2 (2) is described. The compounds (COD)Pt(CH2CMe3)2 (5) and (COD)Pt(CH2SiMe3)2 (6) were characterized by x-ray structure.
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Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics