Recently I am researching about ARYL CHLORIDES; METAL-FREE; ALKENES; ATRA; CYCLIZATION; ALKYNES; INITIATOR; BONDS, Saw an article supported by the National Nature Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21872033, 21643009]; National Basic Research Program of ChinaNational Basic Research Program of China [2014CB239303]; Natural Science Foundation of Fujian Province of ChinaNatural Science Foundation of Fujian Province [2015J01046]; Independent Research Project of State Key Laboratory of Photocatalysis on Energy and Environment [2014B01]. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Pan, H; Ge, HQ; He, R; Huang, WC; Wang, LL; Wei, YC; Sa, RJ; Wang, YJ; Yuan, RS. The CAS is 95-49-8. Through research, I have a further understanding and discovery of 1-Chloro-2-methylbenzene. Formula: C7H7Cl
A photo-induced atom transfer radical addition (ATRA) of aryl chlorides onto alkenes has been developed in the synthesis of chloroalkyl benzenes, in which chlorine radicals and aryl radicals can be generated simultaneously at ambient temperature without the involvement of any initiator or catalyst. The inherently reactive and energetic chlorine radicals also benefit a photo-induced aminocarbonylation reaction of aryl chlorides with carbon monoxide and amines via a hydrogen-abstraction step. These two reactions can provide an inspiration for organic reaction with a radical-designed process. Finally, a photo-induced multi-phase reaction system is extended to flow mode to yield scaled-up products on a gram scale.
Welcome to talk about 95-49-8, If you have any questions, you can contact Pan, H; Ge, HQ; He, R; Huang, WC; Wang, LL; Wei, YC; Sa, RJ; Wang, YJ; Yuan, RS or send Email.. Formula: C7H7Cl
Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
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