I found the field of Chemistry very interesting. Saw the article Catalytic, Asymmetric Dearomative Synthesis of Complex Cyclohexanes via a Highly Regio- and Stereoselective Arene Cyclopropanation Using alpha-Cyanodiazoacetates published in 2020.0. Quality Control of 1-Chloro-2-methylbenzene, Reprint Addresses Johnson, JS (corresponding author), Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA.. The CAS is 95-49-8. Through research, I have a further understanding and discovery of 1-Chloro-2-methylbenzene
Arene cyclopropanation offers a direct route to higher-order, non-aromatic carbocycles; however, the inherent issue of dictating site selectivity has cumbered the development of novel intermolecular reactions that directly engage the arene pool. This paper describes a highly regio- and stereoselective, Rh-2[(S)-PTTL](4)-catalyzed arene cyclopropanation using alpha-cyanodiazoacetates to afford stable norcaradienes bearing three stereogenic centers, one of which is an all-carbon quaternary center. The enantioenriched norcaradienes served as tunable templates for further transformation into stereochemically dense, fused and bicyclic carbocycles containing transmutable functionality.
Quality Control of 1-Chloro-2-methylbenzene. Bye, fridends, I hope you can learn more about C7H7Cl, If you have any questions, you can browse other blog as well. See you lster.
Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics