Recently I am researching about O BOND FORMATION; COUPLING REACTIONS; ENANTIOSELECTIVE SYNTHESIS; CROSS-COUPLINGS; ACTIVATED ARYL; HALIDES; ETHERS; MILD; HYDROXYLATION; PHOTOREDOX, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21871171]; 111 projectMinistry of Education, China – 111 Project [B14041]. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Yang, L; Lu, HH; Lai, CH; Li, G; Zhang, W; Cao, R; Liu, FY; Wang, C; Xiao, JL; Xue, D. The CAS is 95-49-8. Through research, I have a further understanding and discovery of 1-Chloro-2-methylbenzene. Recommanded Product: 1-Chloro-2-methylbenzene
A highly effective C-O coupling reaction of (hetero)aryl electrophiles with primary and secondary alcohols is reported. Catalyzed by a Ni-II-aryl complex under long-wave UV (390-395 nm) irradiation in the presence of a soluble amine base without any additional photosensitizer, the reaction enables the etherification of aryl bromides and aryl chlorides as well as sulfonates with a wide range of primary and secondary aliphatic alcohols, affording synthetically important ethers. Intramolecular C-O coupling is also possible. The reaction appears to proceed via a Ni-I-Ni-III catalytic cycle.
Recommanded Product: 1-Chloro-2-methylbenzene. Welcome to talk about 95-49-8, If you have any questions, you can contact Yang, L; Lu, HH; Lai, CH; Li, G; Zhang, W; Cao, R; Liu, FY; Wang, C; Xiao, JL; Xue, D or send Email.
Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
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