COA of Formula: C7H7Cl. Recently I am researching about C-H AMINATION; N-PHOSPHINYL PHOSPHORAMIDE; INTRAMOLECULAR AMIDATION; BOND ACTIVATION; SIMPLE ETHERS; EFFICIENT; RUTHENIUM(II); PORPHYRINS; COMPLEXES; BIDENTATE, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21571060, 21676076, 21725602]. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Lei, J; Yang, YC; Peng, LT; Wu, LS; Peng, P; Qiu, RH; Chen, Y; Au, CT; Yin, SF. The CAS is 95-49-8. Through research, I have a further understanding and discovery of 1-Chloro-2-methylbenzene
An chelation-assisted oxidative C(sp(3))-H/N-H cross coupling of hydrocarbons with P(O)-NH compounds using copper acetate as catalyst is described. The results of kinetic experiments, mechanistic studies and DFT calculations demonstrate the importance of acetic acid coproduct as an additive for promoting the formation of intermediate bis((diphenylphosphoryl)(quinolin-8-yl)amino)copper (6), and consequently accelerating the construction of C(sp(3))-N bond. The reaction proceeded efficiently with a wide array of hydrocarbons and P(O)-NH compounds, and the rate acceleration induced by the acetic acid coproduct have been repeatedly proven. Furthermore, the efficiency of small-scale reaction could be retained upon gram-scale synthesis in a continuous manner.
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Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
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