An article Cp*Co(iii) and Cu(OAc)(2) bimetallic catalysis for Buchwald-type C-N cross coupling of aryl chlorides and amines under base, inert gas & solvent-free conditions WOS:000599653300011 published article about ONE-POT SYNTHESIS; CARBONYL; REDUCTION; AMINATION; CLUSTERS in [Srivastava, Avinash K.; Sharma, Charu; Joshi, Raj K.] Malaviya Natl Inst Technol, Dept Chem, Jaipur 302017, Rajasthan, India in 2020.0, Cited 34.0. The Name is 1-Chloro-2-methylbenzene. Through research, I have a further understanding and discovery of 95-49-8. Computed Properties of C7H7Cl
A strategy involving bimetallic catalysis with a combination of Cp*Co(CO)I-2 and Cu(OAc)(2) was used for performing Buchwald-type C-N coupling reactions of aryl chlorides with amines. The reactions proceeded at 100 degrees C to produce excellent yields of many of the desired C-N coupled products, in 4 h, under aerobic reaction conditions. The reactions were shown to run under base-free and solvent-free conditions, enabling this strategy to work efficiently for electron-withdrawing and base-sensitive functionalities. The presented methodology was found to be equally efficient for electron-donating functionalities as well as for primary (1 degrees) and secondary (2 degrees) aromatic and aliphatic amines. Moreover, the products were easily separated through the extractions of the organic aqueous layer, with this process chromatographic separations is not required.
Computed Properties of C7H7Cl. Bye, fridends, I hope you can learn more about C7H7Cl, If you have any questions, you can browse other blog as well. See you lster.
Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics